Perpentylated y-cyclodextrin is a very hydrophobic liquid which exhibits enantioselectivity toward a number of non-polar chiral substrates including the saturated hydrocarbons cisand transpinane, P-chiral olefins, iron(0) tricarbonyl complexes of prochiral olefins and 3,3,8,8-tetramethyl-trans-cyclo
Cyclodextrins as chiral stationary phases in capillary gas chromatography. Part IV: Heptakis(2,3,6-tri-O-pentyl)-β-cyclodextrin
✍ Scribed by König, W. A. ;Lutz, S. ;Hagen, M. ;Krebber, R. ;Wenz, G. ;Baldenius, K. ;Ehlers, J. ;Dieck, H. Tom
- Publisher
- John Wiley and Sons
- Year
- 1989
- Tongue
- English
- Weight
- 311 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0935-6304
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The properties of hexa kis(3-0-acetyl-2,6-di-O-pentyl)-a-cyclodextrin as a chiral stationary phase for capillary gas chromatography are described. For the first time the enantiomers of a series of different lactones are separated and their order of elution is assigned. Moreover, the enantiomers of t
2,3-Di-O-pentyl-6-O-tert-butyldimethylsilyl-b-cyclodextrin has been evaluated as an enantioselective stationary phase for capillary gas chromatography. Experimental results show a good enantioselectivity towards compounds with different functional groups (haloalkanes, alcohols, esters, terpenoids, a