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2,3-Di-O-pentyl-6-O-tert-butyldimethylsilyl-β-cyclodextrin as a Chiral Stationary Phase in Capillary Gas Chromatography

✍ Scribed by Miranda, Elena ;Sánchez, Félix ;Sanz, Jesús ;Jiménez, María I. ;Martínez-Castro, Isabel


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
115 KB
Volume
21
Category
Article
ISSN
0935-6304

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✦ Synopsis


2,3-Di-O-pentyl-6-O-tert-butyldimethylsilyl-b-cyclodextrin has been evaluated as an enantioselective stationary phase for capillary gas chromatography. Experimental results show a good enantioselectivity towards compounds with different functional groups (haloalkanes, alcohols, esters, terpenoids, amino acid derivatives, and heterocycles). Column stability improves mixing the chiral phase with polysiloxane SE-54 (1 : 1).


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