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Cyclodehydration of 3-(d-manno-pentitol-1-yl)pyrazoles: Synthesis of 3-(d-arabinofuranosyl)pyrazoles

✍ Scribed by Manuel Gómez-guillén; José María Lassaletta-Simon; María Eloísa Martín-Zamora; Inmaculada Robina

Book ID
102994771
Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
578 KB
Volume
201
Category
Article
ISSN
0008-6215

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✦ Synopsis

Several 3-(D-manno-pentitol-I-yl)pyrazoles were cyclodehydrated by treatment with boiling aqueous 10% trifluoroacetic acid. The products were a&mixtures of 3-(D-arabinofuranosyI)pyrazoles in which the /3 anomer was the major component. The structures and configurations of these C-nucleoside analogues were assigned on the basis of their analytical and spectral data, and those of the triacetates.

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