Cyclopentadienones react with EtO 2 CN S O and related N S reagents to provide ready syntheses of 1,2,5-thiadiazolidines (8, 12, 17), diaminosulfanes (11, 13), an aminocyclopentenone (10) and the first unoxidised 1,2,3-oxathiazolidine ( ), all in a mechanistically rational manner.
Cycloadditions of organic azides to cyclopentadienones
โ Scribed by Alfred Hassner; David J. Anderson; Robert H. Reuss
- Book ID
- 108383131
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- French
- Weight
- 189 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Most Current State-of-the-art Overview Of This Important Class Of Compounds, Encompassing Many New And Emerging Applicationsthe Number Of Articles On Organic Azides Continues To Increase Tremendously; On Average, There Are More Than 1000 New Publications A Yearcovers Basic Chemistry As Well As State
The chemistry of azides starts with the preparation of the fi rst organic azide, phenyl azide, by Peter Griess in 1864 1 and with the discovery of hydrogen azide and the rearrangement of acyl azides to the corresponding isocyanate reported by Curtius in 1890 (Curtius rearrangement). 2 However, only