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Cycloadditions of Allyl Cations, 29. Acid Catalyzed Reactions of 2,3-Dimethyl-3-penten-2-ol and Cyclopentadiene in Two Phases. Formation of Seven- and Five-membered Rings

โœ Scribed by Hoffmann, H. M. R. ;Vathke-Ernst, Heidrun


Publisher
Wiley (John Wiley & Sons)
Year
1981
Tongue
English
Weight
453 KB
Volume
114
Category
Article
ISSN
0009-2940

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Cycloadditions of Allyl Cations, 281)Nov
โœ Hoffmann, H. M. R. ;Vathke-Ernst, Heidrun ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 457 KB ๐Ÿ‘ 1 views

4Methyl-3-penten-2-01 (1) and cyclopentadiene react in an acidic two phase system at 0ยฐC to form allylcyclopentenols 2 and norbornenylcarbinols 4. At 50ยฐC and under similar conditions, 2 as well as 4 are equilibrated to allylcyclopentadienes 3, bicyclic olefins 5 and 6 , and tricyclic ether 7. With