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Cycloadditions. 26. Regio- and stereochemistry of the cycloadditions of dichloroketene to 2-methyl- and 3-methyl-2-cholestene

โœ Scribed by Hassner, Alfred; Krepski, Larry R.

Book ID
121403828
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
457 KB
Volume
44
Category
Article
ISSN
0022-3263

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โœ Rick L. Danheiser; Howard Sard ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 294 KB

Alkynylsilanes undergo regioselective [2+2] cycloadditions with dichloroketene in good yield; the regiochemical course of these reactions is in accord with frontier molecular orbital predictions. Cycloaddition reactions of vinyl-and alkynylsilanes have been employed in expeditious routes to a variet