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Cycloaddition. The Reactions of Δ- 2 -1,2,3-Triazolines with Phenyl Isocyanate and Phenyl Isothiocyanate

✍ Scribed by Baldwin, John E.; Kaiser, Gary V.; Romersberger, Judith A.

Book ID
127247209
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
265 KB
Volume
86
Category
Article
ISSN
0002-7863

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1,3-Thiazepines. Part 2. Reaction of 2-Iminohexahydrothiazepines with Phenyl Isocyanate and Isothiocyanates. -Reaction of the iminothiazepines (I) with phenyl isocyanate (II) gives the expected ureas (III) in good yields. In contrast, reaction with aryl isothiocyanates in refluxing toluene produces