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Cycloaddition Reactions of Chiral 2-Amino-1,3-butadienes with Nitroalkenes: Synthesis of Enantiomerically Pure 4-Nitrocyclohexanones1

✍ Scribed by Barluenga, José; Aznar, Fernando; Ribas, Cristina; Valdés, Carlos

Book ID
111899508
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
210 KB
Volume
62
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Cycloaddition React
ChemInform Abstract: Cycloaddition Reactions of Chiral 2-Amino-1,3-butadienes with Nitroalkenes: Synthesis of Enantiomerically Pure 4-Nitrocyclohexanones.
✍ J. BARLUENGA; F. AZNAR; C. RIBAS; C. VALDES 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 37 KB 👁 1 views

## Cycloaddition Reactions of Chiral 2-Amino-1,3-butadienes with Nitroalkenes: Synthesis of Enantiomerically Pure 4-Nitrocyclohexanones. -Reaction of enantiomerically pure (E)-dienes (I) with nitroalkenes followed by hydrolysis of the resulting enamine furnishes the title compounds diastereosele

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cycloaddition reactions of I-aryl-4-dimethylamino-1,3diaza-1,3-butadienes (~),l-aryl-4-dimethylamino-2-methylthio-l,3-diaza-l,3butadienes 12). l-aryl-4-methylthio-2-phenyl-4-sec.amino-l,3-diaza-l,3butadienes ( 2) and 4, 4-bis~sec.amino~-l,2-diphenyl-l,3-diaza-l,3-bu~adienes 112) with monophenylketen