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2-Amino-1,3-butadienes as chiral building blocks: enantioselective synthesis of 4-piperidones, 4-nitrocyclohexanones, and 1,3-cycloheptadione derivatives

✍ Scribed by Barluenga, Jose; Aznar, Fernando; Valdes, Carlos; Martin, Alfredo; Garcia-Granda, Santiago; Martin, Eduardo


Book ID
121360973
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
277 KB
Volume
115
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Cycloaddition React
✍ J. BARLUENGA; F. AZNAR; C. RIBAS; C. VALDES πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 37 KB πŸ‘ 1 views

## Cycloaddition Reactions of Chiral 2-Amino-1,3-butadienes with Nitroalkenes: Synthesis of Enantiomerically Pure 4-Nitrocyclohexanones. -Reaction of enantiomerically pure (E)-dienes (I) with nitroalkenes followed by hydrolysis of the resulting enamine furnishes the title compounds diastereosele