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Cycloaddition Reactions of 1-Aza- and 1,3-Diazaazulenium 1-Methylides.

โœ Scribed by Hiroyuki Fujii; Izumi Kawano; Kaoru Iwafuji; Yoshiyuki Sawae; Kentaro Nagamatsu; Noritaka Abe

Book ID
102001177
Publisher
John Wiley and Sons
Year
2007
Weight
34 KB
Volume
38
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

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## Abstract Cyclooctyne underwent 1,3โ€dipolar cycloaddition with pyridinium bis(methoxyโ€carbonyl)methylides to afford the corresponding indolizines (8โ€methoxycarbonylโ€7โ€azatricyclo[7.6.0.0^2โ€7^]pentadecaโ€1,3,5,8โ€tetraenes) in good to moderate yields. Some molecular orbital considerations are also d