In contrast to previously reported reactivity of the tungsten pentacarbonyl complex of a 2-substituted 1,2-dihydrophosphete, which apparently undergoes electrocyclic ring opening to the corresponding 1-phospha-1,3-butadiene and subsequent ]2ם4[ cycloaddition reactions with dienophiles, the reactio
Cycloaddition Reactions of 1-Alkyl-3,4,5-triphenyl-1,2-diphosphacyclopenta-2,4-dienes
✍ Scribed by Vasili Miluykov; Ilya Bezkishko; Almaz Zagidullin; Oleg Sinyashin; Peter Lönnecke; Evamarie Hey-Hawkins
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 258 KB
- Volume
- 2009
- Category
- Article
- ISSN
- 1434-193X
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The kinetics of the [2 + + 4] cycloadditions of 1,3-dithian-2-cycloaddition pathway by the correlation lg k = s (E + N). Though a concerted cycloaddition pathway is not excluded ylium ions (1) with 1,3-dienes was investigated photometrically in dichloromethane. The second-order rate by this finding,