In contrast to previously reported reactivity of the tungsten pentacarbonyl complex of a 2-substituted 1,2-dihydrophosphete, which apparently undergoes electrocyclic ring opening to the corresponding 1-phospha-1,3-butadiene and subsequent β«]2Χ4[β¬ cycloaddition reactions with dienophiles, the reactio
ChemInform Abstract: Reactions of 1,3,4-Triphenyl-1,2-dihydrophosphete.
β Scribed by E. M. HANAWALT; K. M. DOXSEE; G. S. SHEN; T. J. R. WEAKLEY; C. B. KNOBLER; H. HOPE
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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Nucleophilicity dominates the reaction chemistry of 1,3,4-triphenyl-1,2-dihydrophosphete even when it is coordinated to electrophilic metal centers, but coordination dramatically alters the course of its reactions. Deoxygenation of carbonyl-containing substrates is effected by both the W(CO) 5 compl
## 1997 triazole derivatives triazole derivatives R 0280 ## 12 -123 Chemical Reactions of the Stable Carbene 1,3,4-Triphenyl-4,5dihydro-1H-1,2,4-triazol-5-ylidene. -Insertion reactions to afford (IV), addition reactions to give (V) and (VII), cycloaddition reactions to yield (IX) and (XI), and r
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