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Cycloaddition Reaction of 2-Vinylazetidines with Benzyne: A Facile Access to 1-Benzazocine Derivatives

โœ Scribed by Aoki, Takashi; Koya, Shunsuke; Yamasaki, Ryu; Saito, Shinichi


Book ID
115521144
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
277 KB
Volume
14
Category
Article
ISSN
1523-7060

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โœ Ashraf A Aly ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 204 KB

Reaction of 4-arylidene-2-phenyl-5(4H)-1,3-oxazolones with benzyne afforded predominantly, 3-arylidene-7-hydroxy-7phenyl-1,4(H)-benzoxazepine-2-ones in addition to their N-phenyl derivatives. However, the reaction of the target oxazolones with an excess of benzyne gave only the N-phenyl derivatives