Reaction of Salicyl N-Tosylimines with 2-Cyclohexenone: A Facile Access to Tetrahydroxanthenones.
โ Scribed by Yong-Ling Shi; Min Shi
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 26 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
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## Abstract A new PPh~3~โcatalyzed synthesis of alkyl 2โ[aryl(tosylimino)methyl]acrylates from propiolate and __N__โtosylimine has been developed. Deuteriumโlabelling experiments show that the reaction mechanism involves several hydrogenโtransfer processes, which are not the turnoverโlimiting step