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Cycloaddition products of tricyclo[6.2.1.02,7]undeca-2(7),4,9-triene-3,6-dione

✍ Scribed by Pattabhi, V. ;Banumathi, S. ;Mehta, G. ;Padma, S.


Book ID
114510553
Publisher
International Union of Crystallography
Year
1994
Tongue
English
Weight
380 KB
Volume
50
Category
Article
ISSN
0108-2701

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Reaction of ArSCl (Ar = phenyl or ortho-nitrophenyl) withendo-tricyclo[6.2.1.@~7]undeca-4,9diene-3,6dione (1) results in arm' addition across the norbcnnene carbon-carbon double bond with concomitant aromatization of the cyclohexenedione ring, thereby affording 4 (87%) and 5 (63%), respectively. Th