## Abstract The reaction between guanine radical cation (G^+ยท^) and carbonate radical anion (CO~3~**^โยท^**) producing the mutagenic product 8โoxoguanine that has been observed experimentally was investigated using density functional and secondโorder MรธllerโPlesset perturbation (MP2) theories. The s
Cycloaddition of the photochemically generated phenylcyclopropaneradical cation to the N-methylnaphthalimide radical anion. mechanism of the reaction.
โ Scribed by Paul H. Mazzocchi; Cathleen Somich
- Book ID
- 108381593
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- French
- Weight
- 190 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
We wish to report that the photochemical decomposition of halogenated N-chloro-and Nbromoacetamides in presence of olefins gives 1,2-adducts in good yields (scheme l), the n-halogen substituents increasing remarkably the tendency of acetylamino radicals to add to double bonds. These results constit
The photomediated generation of a-hydroxyalkyl radicals from simple acyclic and cyclic alcohols, and acyclic diols, and their subsequent carbon-carbon bond forming reaction with propiolate esters and acetylenedicarboxylates, gives a mixture of a b-(hydroxyalkyl)enoate, the result of a formal cis add