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The addition to olefins of acylamino radicals generated by photochemical decomposition of halogenated n-chloro- and n-bromoacetamides

✍ Scribed by D. Touchard; J. Lessard

Publisher: Elsevier Science
Year: 1971
Tongue: French
Weight: 242 KB
Volume: 12
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)97459-3

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✦ Synopsis

We wish to report that the photochemical decomposition of halogenated N-chloro-and Nbromoacetamides in presence of olefins gives 1,2-adducts in good yields (scheme l), the n-halogen substituents increasing remarkably the tendency of acetylamino radicals to add to double bonds.

These results constitute the first examples of photolytic addition of simple N-halocarboxamides to unsaturated compounds in yields of preparative value (1).

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