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Cycloaddition of benzonitrile oxide with some butadienylamines

✍ Scribed by P. Caramella; P. Bianchessi

Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
431 KB
Volume
26
Category
Article
ISSN
0040-4020

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The first diastereoselective cycloaddition of a nitrile oxide with a homoallylic alcohol is discussed. The reaction of benzonitrile oxide with the magnesium alkoxides of chiral homoallylic alcohols has been shown to proceed with good diastereoselectivity, favoring the syn isomer of the resulting 2-i