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Cycloaddition de dienophiles organometalliques au dimethyl-1,1 diphenyl-2,5 silacyclopentadiene

✍ Scribed by A Laporterie; J Dubac; P Mazerolles; M Lesbre

Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
157 KB
Volume
12
Category
Article
ISSN
0040-4039

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📜 SIMILAR VOLUMES

Metall-π-Komplexe des 2, 5-Diphenyl-1-si
Metall-π-Komplexe des 2, 5-Diphenyl-1-silacyclopentadiens
✍ Walter Fink 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 German ⚖ 383 KB

## Abstract The preparation of 2.5‐diphenyl‐1‐silacyclopentadienes and their reaction with iron carbonyls and π‐cyclopentadienyl‐dicarbonylcobalt yielding metal‐π‐silole complexes is described. Mass spectral data indicate the existence of an ‘aromatic’ silacyclopentadienyl species.

Die Struktur des Adduktes aus 3-Dimethyl
Die Struktur des Adduktes aus 3-Dimethylamino-2,2-dimethyl-2H-azirin und 3-Methyl-2,4-diphenyl-1,3-oxazolium-5-olat. Vorläufige Mitteilung
✍ Josef Lukáč; Jost H. Bieri; Heinz Heimgartner 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 German ⚖ 393 KB

**Structure of the adduct from 3‐dimethylamino‐2,2‐dimethyl‐2__H__‐azirine and 3‐methyl‐2,4‐diphenyl‐1,3‐oxazolium‐5‐olate** 3‐Dimethylamino‐2,2‐dimethyl‐2__H__‐azirine (**1**) reacts with 3‐methyl‐2,4‐diphenyl‐1,3‐oxazolium‐5‐olate (**5a**) to give a 1:1 adduct (**7**) in a 88% yield. Its crystal