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cyclo-Triphosphorus (.delta.-P3) as a ligand in cobalt and nickel complexes with 1,1,1-tris(diphenylphosphinomethyl)ethane. Formation and structures

โœ Scribed by Di Vaira, M.; Ghilardi, C. A.; Midollini, S.; Sacconi, L.


Book ID
125898830
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
290 KB
Volume
100
Category
Article
ISSN
0002-7863

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1,3,5-Tris(phenylphospha)-2,4,6-tris(phenylarsa)cyclohexane, cyclo(Ph.&,PB), whose perfectly alternating pnictogen structure was determined by the absence of direct P-P coupling in NMR spectra, reacts with Mo(CO), at 80 "C to form a complex, Mo(CO),[c-(Ph&,P,)], containing completely scrambled pheny