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Synthesis and crystal structure of two isomorphous rhodium and iridium complexes with cyclo-triphosphorus and 1,1,1,-tris(diphenylphosphinomethyl)-ethane

✍ Scribed by C. Bianchini; C. Mealli; A. Meli; L. Sacconi

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
208 KB
Volume
37
Category
Article
ISSN
0020-1693

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The structures of [RhCl(CO)(l)] and [PdC1,(1)], where 1 is the bidentate ligand (C6H5)2P . CH2 . ClsHlo . CH2 . P (C6H5),, have been determined from threedimensional X-ray counter data collected on single crystals of the C6H5. CN solvates. The two compounds are isomorphous and crystallize in the tri