## Abstract For Abstract see ChemInform Abstract in Full Text.
Cyclization of 1-Bromo-2,7- and 1-Bromo-2,8-Enynes Mediated by Indium
β Scribed by Lee, Phil Ho; Kim, Sundae; Lee, Kooyeon; Seomoon, Dong; Kim, Hyunseok; Lee, Seokju; Kim, Misook; Han, Mijeong; Noh, Kwanghyun; Livinghouse, Tom
- Book ID
- 126465233
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 69 KB
- Volume
- 6
- Category
- Article
- ISSN
- 1523-7060
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π SIMILAR VOLUMES
2-Bromo-1,6-enynes 5 with a palladium catalyst would form the alkenylpalladium intermediates via an intramolecular Heck reaction, which were cross-coupled with various organoboronic acids 8 to give the cyclization-coupling products 6 in synthetically valuable yields.
A stereospecific synthesis of fluorinated enynes and dienes was performed through palladium-catalyzed condensation of 1-bromoP-fluoroalkenes, synthesized either through "BrF addition