**Cyclization Reactions of β,γ‐Unsaturated Derivatives of Carbonic Acid. II. Reactions of β,γ‐Unsaturated Carbamic Acid Esters with Electrophilic Reagents — Synthesis of N‐Substituted Oxazolidine‐2‐ones** N,N‐Disubstituted β,γ‐unsaturated urethans have been cyclized to N‐substituted oxazolidine‐2‐o
Cyclisierungsreaktionen β,γ-ungesättigter Kohlensäurederivate. V . Reaktionen β,γ-ungesättigter Carbamidsäureester mit Sulfenylchloriden - Synthese von 3,5,5-trisubstituierten Oxazolidin-2-onen
✍ Scribed by Prof. Dr. M. Mühlstädt; Dr. R. Widera; Dipl.-Chem. B. Olk
- Publisher
- John Wiley and Sons
- Year
- 1982
- Tongue
- English
- Weight
- 417 KB
- Volume
- 324
- Category
- Article
- ISSN
- 1615-4150
No coin nor oath required. For personal study only.
✦ Synopsis
Cyclization Reactions of β,γ‐Unsaturated Derivatives of Carbonic Acid. V. Reactions of β,γ‐Unsaturated Carbamic Acid Esters with Sulfenyl Chlorides — Synthesis of 3,5,5‐Trisubstituted Oxazolidine‐2‐ones
N,N‐Disubstituted β,γ‐Unsaturated urethanes 1 have been cyclized to 3,5,5‐trisubstituted oxazolidine‐2‐ones 3 by aromatic sulfenyl chlorides in methylene chloride. The same oxazolidine‐2‐ones 3 were obtained by reaction of 5‐bromomethyloxazolidine‐2‐ones 8 with thiophenols.
📜 SIMILAR VOLUMES
**Cyclization Reactions of β,γ‐Unsaturated Derivatives of Carbonic Acid. IV. Synthesis of N‐Substituted Thiazolidine‐2‐ones and 2‐Alkoxy‐2‐thiazolines from β,γ‐Unsaturated Thiocarbamic Acid Esters** The reaction between N‐substituted β,γ‐unsaturated thiourethans and dry hydrogen chloride or bromine
**Cyclization Reactions of β,γ‐Unsaturated Derivatives of Carbonic Acid. VII. Synthesis of Unequivocal N‐Acylated Thiazolidine‐2‐ones and Oxazolidine‐2‐ones** A new synthetic route to N‐acylated thiazolidine‐2‐ones and oxazolidine‐2‐ones is reported: The reaction of carboxylic acid chlorides with 2