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Cyclische Sulfoximide, VI. 3-Imino-3H-1λ4,2-benzisothiazol-1-oxide

✍ Scribed by Stoss, Peter ;Satzinger, Gerhard

Publisher
Wiley (John Wiley & Sons)
Year
1975
Tongue
English
Weight
318 KB
Volume
108
Category
Article
ISSN
0009-2940

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✦ Synopsis

Abstract

2‐Sulfinylbenzamide 3 reagieren mit Stickstoffwasserstoffsäure zu 3‐Imino‐3__H__‐1λ^4^,2‐benzisothiazol‐1‐oxiden 4, die durch Substitution am Imin‐Stickstoff die Derivate 9–12 liefern.

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✍ Heider, Walter ;Hoge, Burghard ;Glemser, Oskar 📂 Article 📅 1978 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 397 KB 👁 1 views

The title compound S4) reacts with secondary amines HNR, (R = CH,, C,H,) and N(CH,), in a molar ratio 1 : 1 : 1 to give 9 and 10, with primary amines HzNR (R = CH,, C,H,) and N(CH,), in a molar ratio 1 : 2 : 2 by rearrangement ofan F-atom to form 11 and 12. The P-fluorinated compound 13 is obtained