Cyclisation du dipropényl-2,2′ diphényle et du dipropényl-1,8 naphtalene
✍ Scribed by F. Auclair; A. Kergomard; H. Veschambre; C. Minot
- Book ID
- 103393160
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 639 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0040-4020
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**Facile synthesis of derivatives of 2,4‐diphenyl‐3‐azabicyclo[3.3.1]nonane and 7,9‐diphenyl‐8‐azabicyclo[4.3.1]decane** The facile synthesis of hydantoins, cyanhydrins and aminonitriles derived from 2,4‐diphenyl‐3‐azabicyclo[3.3.1]nonanone and 7,9‐diphenyl‐8‐azabicyclo[4.3.1]decanone is described.
The presence at the mercury cathode of tiny amounts of strongly adsorbed inductors such as strychnin, emetin or yohimbin, leads, after electrochemical halogen abstraction at the sp3 prochiral carbon of the title compound, to a notably optically active product. La 1ittGrature de ces dernikes an&es ra