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Cyclic voltammetric and electrocrystallization studies of biscyanophthalocyaninato metal complexes and related compounds

โœ Scribed by Behnisch, R.; Leverenz, A.; Mangold, K.-M.; Hanack, M.


Book ID
122281685
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
121 KB
Volume
42
Category
Article
ISSN
0379-6779

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fl-Ketooxime [RC(O)C(NOH)R] (R = Me or Ph) ligands (HL) react with [Ru(PPh3)3C12] in refluxing EtOH to yield [Ru(PPh3)2(L)2'] complexes. For R=Me, one isomer was obtained, while two isomers were isolated when R = Ph, due to a bulk effect. The complexes are diamagnetic and absorb intensely in the vis