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Cyclic transition states in cis- and trans-addition of chlorine acetate to olefinic substances

✍ Scribed by de la Mare, P. B. D.; O'Connor, Charmian J.; Rosser, M. J.; Wilson, M. A.


Book ID
118150613
Publisher
Royal Society of Chemistry
Year
1970
Weight
203 KB
Volume
12
Category
Article
ISSN
0577-6171

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The Rh"-catalyzed carbenoid addition of diazoacetates to olefins was investigated with [Rh2{(4S)-phox},] (1; phox = tetrakis[(4S)-tetrahydro-4-phenyloxazol-2-one]), [Rh2{(2S)-mepy},] (2; mepy = tetrakis[methyl (2s)tetrahydro-5-oxopyrrole-2-carboxylate]), and [Rh,(OAc),] (3). While catalysis with 2 a