## Abstract The kinetics of the reactions of ground state oxygen atoms with __trans__‐2‐butene, __cis__‐2‐butene, 2‐methylpropene, 2‐methyl‐2‐butene, and 2,3‐dimethyl‐2‐butene was investigated in the temperature range 200 to 370K. In this range, the rate constants are (in units 10^−11^ cm^3^ s^−1^)
✦ LIBER ✦
Low-temperature oxygen atom addition to olefins. III. Transition state and the reaction with cis- and trans-2-butenes
✍ Scribed by Scheer, Milton D.; Klein, Ralph
- Book ID
- 125861401
- Publisher
- American Chemical Society
- Year
- 1969
- Tongue
- English
- Weight
- 509 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0022-3654
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The kinetics of the reactions of ground state oxygen atoms with 1-pentene, 1-hexene, cis-2pentene, and trans-2-pentene was investigated in the temperature range 200 to 370 K. In this range the temperature dependences of the rate constants can be represented by k ϭ AЈ T n exp(Ϫ E a Ј/RT) with AЈ ϭ (1