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Low-temperature oxygen atom addition to olefins. III. Transition state and the reaction with cis- and trans-2-butenes

✍ Scribed by Scheer, Milton D.; Klein, Ralph


Book ID
125861401
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
509 KB
Volume
73
Category
Article
ISSN
0022-3654

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The kinetics of the reactions of ground state oxygen atoms with 1-pentene, 1-hexene, cis-2pentene, and trans-2-pentene was investigated in the temperature range 200 to 370 K. In this range the temperature dependences of the rate constants can be represented by k ϭ AЈ T n exp(Ϫ E a Ј/RT) with AЈ ϭ (1