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Cyclic Se6 and Helical 1∞[Sex] as Neutral Ligands in the New Compounds PdBr2Se6 and PdCl2Se8.

✍ Scribed by Hans-Joerg Deiseroth; Christof Reiner; Marc Schlosser; Xiaowen Wang; Humayun Ajaz; Lorenz Kienle


Book ID
102017371
Publisher
John Wiley and Sons
Year
2007
Weight
13 KB
Volume
38
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Se17(NbCl6)2 and Se
✍ J. BECK; A. FISCHER 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB 👁 1 views

Se17(NbCl6)2 and Se17(TaBr6)2 -Two New Compounds in the Structure Type Se17(MX6)2. -The novel isotypic title compounds (triclinic, P1, Z = 2) are prepared by reaction of Se, SeX4, and MX5 (X: Cl, M: Nb; X: Br, M: Ta) in SnCl4 and SiBr4, resp., at 150 • C (evacuated glass ampoules). The black crysta