Cyclic phosphonomethylphosphinates: a new type of phosphorus-containing sugars
โ Scribed by Philippe Bisseret; Jean-Guy Boiteau; Jacques Eustache
- Book ID
- 104253155
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- French
- Weight
- 236 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
The first synthesis of arabino-configured cyclic phosphonomethylphosphinates is described. The key step is the condensation of the triethylester of H-phosphinylphosphonate 10 on an hydroxyaldehyde 11 derived from a D-arabinal derivative followed by a cyclization induced under acetylation conditions.
๐ SIMILAR VOLUMES
The first phosphorus-containing crown ethers with regularly alternating arylene and phosphorus acid residues have been obtained. Structural peculiarities and some chemical properties of these compounds have been studied. Rhodium complexes of new phosphorus-containing macrocycles have been prepared.