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Cyclic Control of the Surface Properties of a Monolayer-Functionalized Electrode by the Electrochemical Generation of Hg Nanoclusters

✍ Scribed by Michael Riskin; Bernhard Basnar; Eugenii Katz; Itamar Willner


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
298 KB
Volume
12
Category
Article
ISSN
0947-6539

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The synthesis of the cyclophane-type molecular dyads 1 and 1 . Zn was accomplished by Bingel macrocyclization of porphyrin-tethered bis-malonates 5 or 5 . Zn, respectively, with C 60 ( Scheme). In these macrocycles, the doubly bridged porphyrin adopts a close, tangential orientation relative to the