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Cyanuric chloride promoted oxidation of sulfides to sulfoxides or sulfones in the presence of hydrogen peroxide

โœ Scribed by Lakouraj, Moslem Mansour; Abdi, Hamid; Hasantabar, Vahid

Book ID
120069751
Publisher
Taylor and Francis Group
Year
2011
Tongue
English
Weight
426 KB
Volume
32
Category
Article
ISSN
1741-5993

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TMSCl-promoted selective oxidation of su
TMSCl-promoted selective oxidation of sulfides to sulfoxides with hydrogen peroxide
โœ Kiumars Bahrami; Mohammad M. Khodaei; Behrooz H. Yousefi; Mehdi Sheikh Arabi ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 584 KB

Selective oxidation of sulfides to sulfoxides is achieved using H 2 O 2 and TMSCl as the promotor. Aromatic and aliphatic sulfides are oxidized to sulfoxides in excellent yields and in short reaction times. Different functional groups including ketone, alkene, ester, and alcohol are tolerated.