✦ LIBER ✦

Cyanogen pyrolysis and the CN + NO reaction behind incident shock waves

✍ Scribed by M. B. Colket III

Publisher: John Wiley and Sons
Year: 1984
Tongue: English
Weight: 743 KB
Volume: 16
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550160406

No coin nor oath required. For personal study only.

✦ Synopsis

The reaction chemistry of C,N,-Ar and C,N,-NO-Ar mixtures has been investigated behind incident shock waves. Progress of the reaction was monitored by observing the cyano radical (CN) in absorption a t 388.3 nm. A quantitative spectroscopic model was used to determine concentration histories of CN. From initial slopes of CN concentration during cyanogen pyrolysis, the rate constant for C,N, + M -+ 2CN + M (1) was determined to be K , = (4.11 5 1.8) x 1OI6 exp(-47,070 5 1400/T) cm3/mol . s. A reaction sequence for the C,N,-NO system was developed, and CN profiles were computed. By comparison with experimental CN profiles the rate constant for the reaction CN + NO + NCO + N (3) was determined to be k, = 10"40f03r exp (-21,190 2 1500/T) cm3/mol . s. In addition, the rate of the four-centered reaction CN + NO + N, + CO (2) was estimated to be approximately three orders of magnitude below collision frequency.

📜 SIMILAR VOLUMES

The vibrational excitation of hydrogen f

The vibrational excitation of hydrogen fluoride behind incident shock waves

✍ W. C. Solomon; J. A. Blauer; F. C. Jaye; J. G. Hnat 📂 Article 📅 1971 🏛 John Wiley and Sons 🌐 English ⚖ 299 KB

## Abstract The vibrational excitation of HF occurring behind incident shock waves has been studied in the temperature range of 1400°K to 4100°K. The extent of excitation was determined as a function of time by continuously monitoring the emission intensity from the 1–0 band of HF centered at 2.5 μ

The pyrolysis of 2-, 3-, and 4-methylben

The pyrolysis of 2-, 3-, and 4-methylbenzyl radicals behind shock waves

✍ Ravi X. Fernandes; Andreas Gebert; Horst Hippler 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 178 KB

Direct measurements of the reaction H +

Direct measurements of the reaction H + CH2O → H2 + HCO behind shock waves by means of Vis–UV detection of formaldehyde

✍ Gernot Friedrichs; David F. Davidson; Ronald K. Hanson 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 209 KB 👁 1 views

## Abstract The combination of sensitive detection of formaldehyde by 174 nm absorption and use of ethyl iodide as a hydrogen atom source allowed direct measurements of the reaction H + CH~2~O → H~2~ + HCO behind shock waves. The rate constant was determined for temperatures from 1510 to 1960 K to

Erratum: “Direct measurements of the rea

Erratum: “Direct measurements of the reaction H + CH2O → H2 + HCO behind shock waves by means of V-UV detection of formaldehyde”, Int J Chem Kinet 2002, 34, 374

📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 49 KB 👁 1 views