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The pyrolysis of 2-, 3-, and 4-methylbenzyl radicals behind shock waves

✍ Scribed by Ravi X. Fernandes; Andreas Gebert; Horst Hippler

Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
178 KB
Volume
29
Category
Article
ISSN
1540-7489

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## Abstract 2,4‐Dimethylhexene‐l has been decomposed in single‐pulse shock tube experiments. Rate expressions for the initial reactions are and sec^βˆ’1^ at 1.5–5 atm and 1050Β°K. This leads to Ξ”__H__^Β°^~f300~ (CH~2~ = C(CH~3~)CH~2~) = 124 kJ/mol, or an allylic resonance energy of 50 kJ/mol. Rate