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Cyanation and sulfonylation of 5-substituted tetrazoles. imidoyl azides

✍ Scribed by O. Subba Rao; Walter Lwowski

Book ID
112125917
Publisher
Journal of Heterocyclic Chemistry
Year
1980
Tongue
English
Weight
149 KB
Volume
17
Category
Article
ISSN
0022-152X

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✍ Gerrit L'abbΓ©; Alex van Asch; FranΓ§oise Godts πŸ“‚ Article πŸ“… 2010 πŸ› Wiley (John Wiley & Sons) βš– 93 KB πŸ‘ 2 views

The high reactivity of imidoyl chlorides in nucleophilic displacement reactions is related to their facile isomerization into nitrilium ions.' with the azide ion to give imidoyl azides which may equilibrate with tetrazoles depending on the nature of the substituents, temperature and solvent used. Fo