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Curing kinetics of boron-containing phenol–formaldehyde resin formed from paraformaldehyde

✍ Scribed by Yanfang Liu; Jungang Gao

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
117 KB
Volume
34
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

A boron‐containing phenol–formaldehyde resin (BPFR) was synthesized from boric acid, phenol, and paraformaldehyde. The curing reaction of BPFR was studied by Fourier‐transform infrared spectrometry and differential scanning calorimetry. According to the heat evolution behavior during the curing process, several influencing factors on isothermal curing reaction were evaluated. The results show that the isothermal kinetic reaction of BPFR follows autocatalytic kinetics mechanism, and kinetic parameters m, n, k~1~, and k~2~, were derived, respectively. In the latter reaction stage, the curing reaction becomes controlled mainly by diffusion. © 2002 Wiley Periodicals, Inc. Int J Chem Kinet 34: 638–644, 2002

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