Extremely high diastereomeric excess was achieved from the photosensitized polar addition of methanol to (R)-(+)limonene 1. Diastereomeric excess was varied from 28.1 to 96.3% depending on the solvent polarity, reaction temperature, and structure of sensitizer.
β¦ LIBER β¦
Cumulene photochemistry: photoaddition of neutral methanol to phenylallenes
β Scribed by Michael W. Klett; Richard P. Johnson
- Book ID
- 104220135
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- French
- Weight
- 213 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0040-4039
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