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Photochemistry of acetylenes. I. Photoaddition of ethylene to dimethyl acetylenedicarboxylate

โœ Scribed by Bloomfield, Jordan J.; Owsley, Dennis C.

Book ID
127281637
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
346 KB
Volume
93
Category
Article
ISSN
0002-7863

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The reactions have been studied by a mass-balance method involving the photolysis of small amounts of biacetyl in the presence of a large excess of isobutane containing a small proportion of the unsaturated substrate. The following Arrhenius parameters have been derived: Temperature Reaction E log A