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Cu(I)/Cu(II)-catalyzed allylic amination of alkenes

โœ Scribed by Radhey S. Srivastava; Roy Bertrand III; August A. Gallo; Kenneth M. Nicholas

Book ID
104099250
Publisher
Elsevier Science
Year
2011
Tongue
French
Weight
477 KB
Volume
52
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Allylic hydrocarbons are selectively converted to the corresponding allyl amines in good to excellent yield by reaction with aryl hydroxylamines catalyzed by a 1:1 mixture of CuCl and CuCl 2 (10 mol %). Under these conditions unsymmetrical olefins react highly regioselectively with N-functionalization at the less substituted vinylic carbon. Trapping experiments indicate that a free nitrosoarene is not an intermediate in these reactions.

๐Ÿ“œ SIMILAR VOLUMES

ChemInform Abstract: Cu(I)/Cu(II)-Cataly
ChemInform Abstract: Cu(I)/Cu(II)-Catalyzed Allylic Amination of Alkenes.
โœ Radhey S. Srivastava; Roy III Bertrand; August A. Gallo; Kenneth M. Nicholas ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 1 views

## Abstract Unsymmetrical olefins react highly regioselectively with phenyl hydroxylamine.

Cu(I)-catalyzed allylic amination of ole
Cu(I)-catalyzed allylic amination of olefins
โœ Gregg A Hogan; August A Gallo; Kenneth M Nicholas; Radhey S Srivastava ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 272 KB

The copper(I) complex [Cu(CH 3 CN) 4 ]PF 6 catalyzes the allylic amination of alkenes by aryl hydroxylamine in fair to moderate yields. Unsymmetrical alkenes react with high regioselectivity with N-functionalization occuring at the less substituted vinylic carbon. Trapping experiments indicate that

Cu(I)-Catalyzed Allylic Amination of Ole
Cu(I)-Catalyzed Allylic Amination of Olefins.
โœ Gregg A. Hogan; August A. Gallo; Kenneth M. Nicholas; Radhey S. Srivastava ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› John Wiley and Sons โš– 136 KB ๐Ÿ‘ 2 views
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โœ Vince S. C. Yeh; Paul E. Wiedeman ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› John Wiley and Sons โš– 27 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.