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Cu(I)-Mediated Reductive Amination of Boronic Acids with Nitroso Aromatics

โœ Scribed by Yu, Ying; Srogl, Jiri; Liebeskind, Lanny S.


Book ID
121304962
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
60 KB
Volume
6
Category
Article
ISSN
1523-7060

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Simple and chemoselective reduction of a
โœ J.S.Dileep Kumar; ManKit M Ho; Tatsushi Toyokuni ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 82 KB

Reduction of aromatic nitro compounds to amines with hydriodic acid was reinvestigated. Under a milder non-refluxing condition (at 90ยฐC for 2-4 h), the reduction proceeded efficiently with excellent chemoselectivity without affecting other functional groups including nitrile, ester, halide, carbonyl