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CuH-Catalyzed Enantioselective 1,2-Reductions of α,β-Unsaturated Ketones

✍ Scribed by Moser, Ralph; Bošković, Žarko V.; Crowe, Christopher S.; Lipshutz, Bruce H.


Book ID
121182441
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
225 KB
Volume
132
Category
Article
ISSN
0002-7863

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ChemInform Abstract: CuH-Catalyzed Enant
✍ Ralph Moser; Zarko V. Boskovic; Christopher S. Crowe; Bruce H. Lipshutz 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 70 KB 👁 1 views

## Abstract Under optimized conditions, a variety of ketones undergo asymmetric 1,2‐reductions almost exclusively instead of the normally observed 1,4‐reductions in the presence of in situ‐generated CuH which is ligated with an optically active bisphosphane ligand.

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