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[Cu36I56]20⊖—a Novel Polyanion in the Compound (pyH)2[Cu3I5]

✍ Scribed by Prof. Dr. Hans Hartl; Prof. Dr. Joachim Fuchs

Book ID
101553985
Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
247 KB
Volume
25
Category
Article
ISSN
0044-8249

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In situ synthesis, structural characteri
In situ synthesis, structural characterization and luminescent property of a novel hybrid solid with twofold interpenetrating (4,6)-connected topology [{(Cu4I4)2H2O}{Cu6(mtz)6}]n (Hmtz = 3,5-dimethyl-1,2,4-triazole)
✍ Yunlong Fu; Hui Lu 📂 Article 📅 2008 🏛 Elsevier Science 🌐 English ⚖ 382 KB

A novel three-dimensional hybrid solid, [{(Cu 4 I 4 ) 2 H 2 O}{Cu 6 (mtz) 6 }] n (1) (Hmtz = 3,5-dimethyl-1,2,4-triazole), was synthesized under solvothermal condition. The structure of 1 consists of four-connected Cu 4 I 4 clusters and hexanuclear Cu 6 (mtz) 6 rings as secondary building units (SBU