Cu1.5[Cr(CN)6]⋅6.5H2O nanoparticles: synthesis, characterization, and magnetic properties
✍ Scribed by Amit Kumar; S. M. Yusuf; J. V. Yakhmi
- Publisher
- Springer
- Year
- 2009
- Tongue
- English
- Weight
- 515 KB
- Volume
- 99
- Category
- Article
- ISSN
- 1432-0630
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## Abstract Two unprecedented open‐framework polar compounds (C~6~NO~2~H~5~)~2~[Ln(H~2~O)~5~(CrMo~6~H~6~O~24~)]·0.5H~2~O [Ln = Ce (1), La (2); C~6~NO~2~H~5~ = pyridine‐3‐carboxylic acid], constructed from Anderson‐type polyoxo anions and rare‐earth cations, have been synthesized for the first time
Cu 4 (succinato)(tpmc) 2 ](ClO 4 ) 6 AE 2H 2 O (tpmc = N,N 0 ,N 00 ,N 000 -tetrakis-(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane, succinato = dianion of succinic acid) has been prepared and characterized by elemental analysis, UV/vis, IR, EPR (X-band) spectra, conductivity and magnetization m