Cu titration of tilted CO on a Mo(110) surface
โ Scribed by J.-W. He; W.K. Kuhn; D.W. Goodman
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 327 KB
- Volume
- 177
- Category
- Article
- ISSN
- 0009-2614
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Alternate surface reaction channels involving CO dissociation and the inhibition of dissociation on Mo( 110) have been detected directly by vibrational studies using EELS. The CO species that exhibit au (CO ) of 1345 cm-' can be converted completely to adsorbed atomic carbon and atomic oxygen via an
The dependence of the vibrational stretching frequency, toe, of CO adsorbed on compressed or expanded Cu(lO0) layers has been studied theoretically by means of ab initio cluster model wavefunctions. It is found that even moderate changes in the surface distances result in measurable shifts in toe(CO