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Cu-catalyzed regioselective carbomagnesiation of dienes and enynes with sec- and tert-alkyl Grignard reagents

✍ Scribed by Todo, Hirohisa; Terao, Jun; Watanabe, Hideyuki; Kuniyasu, Hitoshi; Kambe, Nobuaki


Book ID
118063156
Publisher
Royal Society of Chemistry
Year
2008
Tongue
English
Weight
361 KB
Volume
11
Category
Article
ISSN
1359-7345

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In the presenceof PdC12(PPb3)2 and Et3N,cbloroenynesandchlorodienesreact rapidly under mild conditions with various Grignard reagents to give isometricallypure conjugated enynes, dienes, dienynesandtrienes in goodisolatedyields. 01997 Publishedby Elsevier Science Ltd.