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ChemInform Abstract: Cu-Catalyzed Regioselective Carbomagnesiation of Dienes and Enynes with sec- and tert-Alkyl Grignard Reagents.

โœ Scribed by Hirohisa Todo; Jun Terao; Hideyuki Watanabe; Hitoshi Kuniyasu; Nobuaki Kambe


Publisher
John Wiley and Sons
Year
2008
Weight
46 KB
Volume
39
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Phosphine-Directed
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Phosphine-Directed Stereo-and Regioselective Ni-Catalyzed Reactions of Grignard Reagents with Allylic Ethers. -In the presence of a properly positioned internal Lewis base like a phosphine unit various acyclic and cyclic allylic ethers are regio-and stereoselectively methylated or phenylated. Under