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Cu-Catalyzed Oxidative Amidation of Propiolic Acids Under Air via Decarboxylative Coupling

✍ Scribed by Jia, Wei; Jiao, Ning


Book ID
115545134
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
238 KB
Volume
12
Category
Article
ISSN
1523-7060

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Symmetric diarylalkynes were obtained from the decarboxylative coupling reactions of aryl bromides and propiolic acid in water solvent condition. In the presence of phase transfer surfactant C 18 H 37 N(CH 3 ) 3 Cl, the catalytic system of both Pd(PPh 3 ) 2 Cl 2 /dppb and Pd(TPPMS) 2 Cl 2 /TPPMS aff