Cs3Mo5P6O25: a Novel Molybdenum Phosphate Containing a Cubane-like Mo4O4 Cluster with Six Molybdenum-Molybdenum Bonds
โ Scribed by Dr. Kwang-Hwa Lii; Dr. Robert C. Haushalter; Professor Charles J. O'Connor
- Publisher
- John Wiley and Sons
- Year
- 1987
- Tongue
- English
- Weight
- 347 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
A new mixed-valent molybdenum monophosphate Li 3 Mo 3 O 5 (PO 4 ) 3 with an original structure has been isolated. It crystallizes in the space group P1 with a โซุโฌ 11.964, b โซุโฌ 12.716, c โซุโฌ 8.274 A s , โซุโฌ 90.26ยฐ, โซุโฌ 96.87ยฐ, and โซุโฌ 89.67ยฐ. It is to date the only mixed-valent molybdenum phosphate
A novel molybdenum(V) phosphate decorated with nickel complex cations, Ni[Mo 6 O 12 (OH) bipy๏ผ2,2'-bipyridyl), has been hydrothermally synthesized and characterized by IR, TGA and single-crystal X-ray diffraction. Two {Mo 6 P 4 } clusters are linked via one Ni cation to form a Ni[Mo 6 P 4 ] 2 dimer