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Crystallographic, thermoelectric, and mechanical properties of polycrystalline type-I Ba8Al16Si30-based clathrates

✍ Scribed by Anno, Hiroaki; Hokazono, Masahiro; Shirataki, Ritsuko; Nagami, Yuko


Book ID
118801467
Publisher
Springer
Year
2012
Tongue
English
Weight
721 KB
Volume
48
Category
Article
ISSN
0022-2461

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A joint experimental and theoretical investigation is performed for Ba-Sn-Ga type-I and type-VIII clathrates. The type-I sample shows a semiconductor characteristic which is accords with the first principle simulation. The type-I clathrate follows Zintl-like behaviour and the semiconducting gap is a