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Thermoelectric properties and structural instability of type-I clathrate Ba8Ga16Sn30 at high temperatures

✍ Scribed by Y. Saiga; K. Suekuni; B. Du; T. Takabatake

Book ID
119373321
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
473 KB
Volume
152
Category
Article
ISSN
0038-1098

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Electronic structure and physical properties of Ba8Ga16Sn30 clathrates with type-I and type-VIII structure
✍ Yang Li; J. Gao; N. Chen; Y. Liu; Z.P. Luo; R.H. Zhang; X.Q. Ma; G.H. Cao πŸ“‚ Article πŸ“… 2008 πŸ› Elsevier Science 🌐 English βš– 163 KB

A joint experimental and theoretical investigation is performed for Ba-Sn-Ga type-I and type-VIII clathrates. The type-I sample shows a semiconductor characteristic which is accords with the first principle simulation. The type-I clathrate follows Zintl-like behaviour and the semiconducting gap is a